###### Question:

Acyl peroxides are commonly used as initiators in radical processes but react in 6) interesting ways in absence of a substrate. Propose a complete mechanism that explains the following decomposition. 2 CO2
7) Halogen abstraction is preferred over hydrogen abstraction by tin radicals (RaSn-). Propose a complete mechanism for the following transformation: Br BugSnH ROOR BugSnH tributyltin hydride
8) The benzylic bromination of A is expected to give mainly compound B but, in practice, product C is the major product. Explain the formation of product C using a reasonable mechanism Br NBS AIBN Br C

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