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B) General chemistry textbooks often show this simplified derivation of the van't Hoff equation A, G...

Question:

b) General chemistry textbooks often show this simplified derivation of the vant Hoff equation A, G In Kp - dln K Then, unde

b) General chemistry textbooks often show this simplified derivation of the van't Hoff equation A, G In Kp - dln K Then, under the assumption that Д.Ho and Δ,So are independent of temperature dln K, However, the Gibbs-Helmholtz equation and, correspondingly, the van't Hoff equation, is a general re- lationship that gives the proper expression for the derivative of Kp at a specific temperature even when ΔΤΗ"and Δ,So are functions of temperature, i.e., when Δ7"Ho Δ,Ho(T) and Δ,So-Δ7S®(T) Show, directly (i.e., without using the Gibbs-Helmholtz equation), that: dln K, RT2 Hint: Since ΔΤ.H"(T) and ΔΤ'S®(T) are both temperature-dependent, you're going to need to use the prod- uct rule when you take the derivative. And you're then going to need to show that these two temperature- dependencies somehow cancel out

Answers

b) Given RT R. ttont dT Hant

.

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